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Biomass Energy TechnologyWood Energy DataThermo-Chemical ProcessThermo-chemical processes convert biomass into higher-value or more convenient products. The process releases a gas, an oil-like liquid and/or a char, and depending on the technology one of these is the final product. Charcoal production is the most common form of thermo-chemical processes. For other processes (e.g. gasification, bio-diesel), extensive research is being carried out, and applications of the technologies can be found in a number of countries (mainly small scale applications). Pyrolysis - Charcoal production - Gasification PyrolysisPyrolysis is the breakdown of biomass in the absence of oxygen at temperatures above 250C. The process produces a solid (char or charcoal), a liquid (bio-oil) and a mixture of gases. The ratio of the products varies with the chemical composition of the biomass and the operating conditions. For example the pyrolysis of 1 tonne european hardwood, gives about 350kg charcoal, 450kg bio-oil, 75kg tar and 60m3 gas. Fast or flash pyrolysis is used to maximise either gas or liquid products according to the temperature employed. Much of the present interest in pyrolysis focuses on its liquid output (bio-oil) due to its high energy density (energy per unit of volume) and potential for liquid fuel substitution, but as of yet this technology remains in its development stage. There has been little research and development for small scale applications. Charcoal productionCharcoal is produced in kilns via a form of pyrolysis. Efficiencies are generally low, but charcoal has advantages over fuelwood like easier distribution, high heat to weight ratio and more convenient. The oldest and probably still most widely used method for charcoal production is the earth kiln (earth pit kiln, earth mound kiln). Several other types of charcoal kilns have been developed, which generally have higher efficiencies but also require higher investments. Two often-used types are the fixed kilns made of mud, clay, bricks, and portable steel kilns.
GasificationGasification is a form of pyrolyses and is the complete thermal breakdown of biomass into a combustible gas, volatiles and ash in an enclosed reactor or gasifier. The gas produced can be used either for heat generation or for power generation. Biomass gasification is normally practised at a relatively small scale, but systems exist up to 50 MWe. High system efficiencies (up to 50%) are achievable using combined cycle gas turbine systems. A wide range of biomass materials (wood, charcoal, coconut shells, rice husk) can be used to fuel gasifiers. Typically 1kg of air dried biomass gives 3-3.6kWh heat, or 0.7-0.9kWh electricity plus 1.4kWh heat. Commercial gasifiers are available in a range of size and types. The Indian Government had a large programme providing small (5-100kW) locally manufactured gasifier units for irrigation. Locally manufactured gasifiers were also made in Thailand and Indonesia.
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